Gold trifluoromethyl complexes
نویسندگان
چکیده
منابع مشابه
Dalton Transactions Perspective Gold Trifluoromethyl Complexes
This article reviews the synthesis, reactivity and applications of gold trifluoromethyl complexes, which are the only isolated perfluoroalkyl complexes of gold. The most reported examples are neutral Au(I) complexes of the type [Au(CF3)L], whereas only two Au(II) trifluoromethyl complexes have been reported, both being diamagnetic and containing a strong Au–Au bond. A number of Au(III) trifluor...
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Organometallic Ni(III) intermediates have been proposed in several Nickel-catalyzed cross-coupling reactions, yet no isolated bis(hydrocarbyl)Ni(III) complexes have been reported to date. Herein we report the synthesis and detailed characterization of stable organometallic Ni(III) complexes that contain two trifluoromethyl ligands and are supported by tetradentate N-donor ligands (R)N4 (R = Me ...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2015
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c5dt02023a